This thesis work epitomizes our experience in the solution structure investigation of chiral lanthanide complexes through a dual paramagnetic NMR/chiroptical spectroscopies method. During my work I have studied the LnM(hfbc)4 system (M alkali metal, hfbc = heptafluorobutyrilcamphorate) and pointed out the connection between the solution structure and its glum dissymetry factor. I have also pointed out a novel effect of enhancement of the VCD signal in presence of a paramagnetic Ln ion for chiral complexes or chiral adducts with natural occuring chiral organic molecules.
Synthesis, structural and dynamic investigation of chiral metal complexes
2013
Abstract
This thesis work epitomizes our experience in the solution structure investigation of chiral lanthanide complexes through a dual paramagnetic NMR/chiroptical spectroscopies method. During my work I have studied the LnM(hfbc)4 system (M alkali metal, hfbc = heptafluorobutyrilcamphorate) and pointed out the connection between the solution structure and its glum dissymetry factor. I have also pointed out a novel effect of enhancement of the VCD signal in presence of a paramagnetic Ln ion for chiral complexes or chiral adducts with natural occuring chiral organic molecules.File in questo prodotto:
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Utilizza questo identificativo per citare o creare un link a questo documento:
https://hdl.handle.net/20.500.14242/131168
Il codice NBN di questa tesi è
URN:NBN:IT:UNIPI-131168