The current study focused on the high-temperature oxidation characteristics of Ni and Co-based superalloys in dry and wet conditions, using both continuous and discontinuous approaches. In the dry high-temperature oxidation state, a continuous flow of air flows inside the furnace, whereas in the wet high-temperature oxidation condition, a mixture of air and water vapor streams inside the furnace at 982 °C. In the continuous approach, all samples were placed inside a furnace at 982°C with a continuous flow of air and water vapor and extracted after a specific time such as 500, 1000, 2000, 3000, and 4000 hours, whereas, in the discontinuous approach, all samples were extracted and reinserted into the furnace after each week at 500, 1000, 2000, 3000, and 4000 hours. The oxide thickness, phases, nature, composition, and morphology of oxides were assessed by energy dispersive x-ray spectroscopy (EDS), optical microscopy, scanning electron microscopy (SEM), weight gain analysis, oxide thickness analysis, and x-ray diffraction (XRD).

The current study focused on the high-temperature oxidation characteristics of Ni and Co-based superalloys in dry and wet conditions, using both continuous and discontinuous approaches. In the dry high-temperature oxidation state, a continuous flow of air flows inside the furnace, whereas in the wet high-temperature oxidation condition, a mixture of air and water vapor streams inside the furnace at 982 °C. In the continuous approach, all samples were placed inside a furnace at 982°C with a continuous flow of air and water vapor and extracted after a specific time such as 500, 1000, 2000, 3000, and 4000 hours, whereas, in the discontinuous approach, all samples were extracted and reinserted into the furnace after each week at 500, 1000, 2000, 3000, and 4000 hours. The oxide thickness, phases, nature, composition, and morphology of oxides were assessed by energy dispersive x-ray spectroscopy (EDS), optical microscopy, scanning electron microscopy (SEM), weight gain analysis, oxide thickness analysis, and x-ray diffraction (XRD).

Evaluation of the degradation mechanisms of materials/coatings of gas turbine components of turbomachinery operating with unconventional fuels

MAITLA, MAIRAJ AHMAD
2025

Abstract

The current study focused on the high-temperature oxidation characteristics of Ni and Co-based superalloys in dry and wet conditions, using both continuous and discontinuous approaches. In the dry high-temperature oxidation state, a continuous flow of air flows inside the furnace, whereas in the wet high-temperature oxidation condition, a mixture of air and water vapor streams inside the furnace at 982 °C. In the continuous approach, all samples were placed inside a furnace at 982°C with a continuous flow of air and water vapor and extracted after a specific time such as 500, 1000, 2000, 3000, and 4000 hours, whereas, in the discontinuous approach, all samples were extracted and reinserted into the furnace after each week at 500, 1000, 2000, 3000, and 4000 hours. The oxide thickness, phases, nature, composition, and morphology of oxides were assessed by energy dispersive x-ray spectroscopy (EDS), optical microscopy, scanning electron microscopy (SEM), weight gain analysis, oxide thickness analysis, and x-ray diffraction (XRD).
28-mag-2025
Inglese
The current study focused on the high-temperature oxidation characteristics of Ni and Co-based superalloys in dry and wet conditions, using both continuous and discontinuous approaches. In the dry high-temperature oxidation state, a continuous flow of air flows inside the furnace, whereas in the wet high-temperature oxidation condition, a mixture of air and water vapor streams inside the furnace at 982 °C. In the continuous approach, all samples were placed inside a furnace at 982°C with a continuous flow of air and water vapor and extracted after a specific time such as 500, 1000, 2000, 3000, and 4000 hours, whereas, in the discontinuous approach, all samples were extracted and reinserted into the furnace after each week at 500, 1000, 2000, 3000, and 4000 hours. The oxide thickness, phases, nature, composition, and morphology of oxides were assessed by energy dispersive x-ray spectroscopy (EDS), optical microscopy, scanning electron microscopy (SEM), weight gain analysis, oxide thickness analysis, and x-ray diffraction (XRD).
Lo studio attuale si è concentrato sulle caratteristiche di ossidazione ad alta temperatura di superleghe a base di Ni e Co in condizioni a secco e a umido, utilizzando approcci sia continui che discontinui. Nello stato di ossidazione ad alta temperatura a secco, un flusso continuo di aria scorre all'interno del forno, mentre nella condizione di ossidazione ad alta temperatura a umido, una miscela di aria e vapore acqueo fluisce all'interno del forno a 982 °C. Nell'approccio continuo, tutti i campioni sono stati inseriti in un forno a 982 °C con un flusso continuo di aria e vapore acqueo ed estratti dopo un tempo specifico, ad esempio 500, 1000, 2000, 3000 e 4000 ore, mentre nell'approccio discontinuo, tutti i campioni sono stati estratti e reinseriti nel forno dopo ogni settimana a 500, 1000, 2000, 3000 e 4000 ore. Lo spessore dell'ossido, le fasi, la natura, la composizione e la morfologia degli ossidi sono stati valutati mediante spettroscopia a raggi X a dispersione di energia (EDS), microscopia ottica, microscopia elettronica a scansione (SEM), analisi dell'aumento di peso, analisi dello spessore dell'ossido e diffrazione dei raggi X (XRD).
Pulci, Giovanni
MARRA, FRANCESCO
SARASINI, Fabrizio
Università degli Studi di Roma "La Sapienza"
188
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14242/312709
Il codice NBN di questa tesi è URN:NBN:IT:UNIROMA1-312709