This work explores palladium‑based systems in homogeneous catalysis, focusing on CO‑mediated transformations and the role of nitrogen ligands. Building on the efficiency of palladium-phenanthroline catalytic system in reductive cyclization of nitroarenes, the study investigates CO and its surrogates as reductant for the synthesis of different nitrogen-containing heterocycles. Furthemore, the use of guanidines as ligands in carbonylation and alkoxycarbonylation of olefins has been attempted.
PALLADIUM-BASED SYSTEMS IN HOMOGENEOUS CATALYSIS: EXPLORING NITROGEN LIGANDS FOR CO-MEDIATED REACTIONS
GALIE, SIMONE
2026
Abstract
This work explores palladium‑based systems in homogeneous catalysis, focusing on CO‑mediated transformations and the role of nitrogen ligands. Building on the efficiency of palladium-phenanthroline catalytic system in reductive cyclization of nitroarenes, the study investigates CO and its surrogates as reductant for the synthesis of different nitrogen-containing heterocycles. Furthemore, the use of guanidines as ligands in carbonylation and alkoxycarbonylation of olefins has been attempted.File in questo prodotto:
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Utilizza questo identificativo per citare o creare un link a questo documento:
https://hdl.handle.net/20.500.14242/356971
Il codice NBN di questa tesi è
URN:NBN:IT:UNIMI-356971