Characterization of advanced materials for low-frequency Vibrational Energy Harvesting (VEH)

Nowadays sensors are among the most exploited systems in everyday life, with several applications stimulating an increasing amount of research. They generally require external power, thus adding issues such as maintenance and size constraints. The most promising energy harvesting (EH) technology for miniaturization is Reverse Electro wetting on Dielectric (REWoD). It can provide high power density by exploiting the mechanical modulation of the capacity at the liquid/dielectric interface attaining, without any external bias, power densities of  µW/cm2. With respect to other EH techniques, REWoD harvests energy from low frequency vibrations (< 10Hz, human motion). I exploited low-cost materials as proof of concept of the feasibility of vibrational EH, suitable for wearable devices, using highly hydrophobic Al and PVDF coated electrodes in combination with polyacrylamide (PAAm) hydrogels loaded with LiCl solutions. The morphology at the sub-micrometer scale and the composition of the outer layers of Al have been studied as a function of the chemical etching time and have been correlated with the surface wettability. The etched Al surfaces exhibit binary structures with nanoscale block-like convexes and hollows, providing more space for air trapping. The analysis shows not only that the change in wetting behaviour correlates with the amount of Al hydroxide at the surface, but also confirms the essential role of the adsorption of airborne carbon compounds. The hydrophobic behaviour depends therefore on the combined effects of surface morphology and surface chemical composition. To compensate for the degradation of the hydrogels with time due to the microstructure of the external oxide layer, an alternative bare Al electrode covered with PVDF has been tested: PAAm hydrogels show now no degradation with time while being able to provide, at frequencies lower than 10 Hz, a peak power/unity of 0.6 Watt, higher than 0.25 Watt, obtained by using the Al oxide electrode.